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The research activities were possible thanks to the financial support received under Project PID2021-124021OB-I00 (URBRAINTREAT), funded by MCIN/AEI/10.13039/501100011033 and "ERDF: A way of making Europe".

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Chestnut Waste-Derived Fe-Based Photocatalyst for Diclofenac Degradation

Publicado en:C-Journal Of Carbon Research. 11 (2): 38- - 2025-06-06 11(2), DOI: 10.3390/c11020038

Autores: Guagliano, Marianna; Bahamonde, Ana; Bellotto, Maurizio; Cristiani, Cinzia; Finocchio, Elisabetta; Gasco, Antonio; Muelas-Ramos, Virginia; Jimenez-Bautista, Karla; de los Rios, Christian; Hermosilla, Daphne

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Resumen

This study aims to demonstrate the feasibility of the use of chestnut waste as a green and circular material for developing iron-based photocatalysts for non-steroidal anti-inflammatory drug (NSAID) photodegradation. Four Fe-based catalysts and two pristine biochars were obtained upon a pyrolysis process at 500 and 700 degrees C and fully characterised. Due to the applied synthesis, iron is present in the form of isotropic grains of magnetite (Fe3O4), quite homogeneously dispersed onto the biochar. The textural properties of all the materials are mainly determined by the pyrolytic temperature, which results in macroporous materials at 500 degrees C and microporous ones at 700 degrees C. Fe-based catalysts were tested in Diclofenac (DFC) photodegradation. DFC removal was the result of both adsorption and photocatalytic reactions. Despite the good yield in DFC removal (80-100%), the formation of degradation by-products can partially invalidate the good effectiveness of this approach. However, the encouraging results of this study represent a step forward for the possible development of waste-derived biochar-based catalysts for in-field application.

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