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This research was funded by the Comunidad de Madrid through the "PANTOMIME" (APOYO-JOVENES-21-9FOMOQ-22-0CNGFM), "DISENO Y FABRICACION DE DISPOSITIVOS FOT & Oacute;NICOS" (BEAGALINDO-21-QU81R4-7-0QQBF3) and the "Ayudas para la realizacion de Doctorados Industriales de la Comunidad de Madrid" (IND2020/TIC-17424). The financial support to this study has also come from the Spanish Government, "ENHANCE-5G" (PID2020-114172RB-C22), "LC-LENS" (PDC2021-121370-C21), "DISRADIO" (TSI-063000-2021-83) and WOW-2D (PLEC2022-009381), as well as the Attract-IALL EU project G.A 101004462 and "CONCEPT-2D" (G.A. 101062995), financed by the European Union. In addition, authors are grateful to the European Space Agency (ESA) for the financial support received with the "Smart Heaters" project (4000133048/20/NL/KML). M.C.G is grateful to Spanish government grant (BG20/00136). The authors thank Prof. Jose Manuel Oton for his contribution in reviewing this article.

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Generation of arbitrarily patterned polarizers using 2-photon polymerization

Publicado en:Scientific Reports. 14 (1): 22550- - 2024-09-29 14(1), DOI: 10.1038/s41598-024-73946-z

Autores: Ganazhapa, B; Pereiro-García, J; Arregui, XQ; Geday, MA; Guadaño, G; Caño-García, M

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Resumen

Patterned polarizers are prepared using liquid crystals (LC) doped with a black dichroic dye and in combination with a linear polarizer. The pattern is achieved with a nanostructured LC alignment surface, that is generated using a two-photon polymerization direct laser write (2PP-DLW). This technique creates a pattern of high-resolution grooves in the photoresist at any arbitrary angle. The angle governs the LC orientation at any substrate surface point, determining the transmitted light linear polarization angle. This paper presents the first use of a 2PP-DLW cured positive tone photoresist for dichroic dye-doped LC alignment. Two complementary photoresists have been employed: conventional negative tone SU-8 photoresist and, in this context novel, positive tone S1805 photoresist. The alignment quality of the polarizers has been assessed by analyzing the transmission using an additional polarizer. For SU-8, the resulting grayscale pattern and a contrast ratio (CR) of 14 has measured. The uniformity of the alignment has been measured to be 65% using normalized Shannon entropy (H). For S1805, a CR of 37 was measured, and a uniformity of 63% was obtained. 2PP-DLW allows for shaping complex patterns in submicron dimensions and for the fabrication of arbitrarily patterned polarizers and other LC devices.

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